Dynamical obstruction in a constrained system and its realization in lattices of superconducting devices

Hard constraints imposed in statistical mechanics models can lead to interesting thermodynamical behaviors, but may at the same time raise obstructions in the thoroughfare to thermal equilibration. Here we study a variant of Baxter's 3-color model in which local interactions and defects are included, and discuss its connection to triangular arrays of Josephson junctions of superconductors and \textit{kagom\'e} networks of superconducting wires. The model is equivalent to an Ising model in a hexagonal lattice with the constraint that the magnetization of each hexagon is $\pm 6$ or 0. For ferromagnetic interactions, we find that the system is critical for a range of temperatures (critical line) that terminates when it undergoes an exotic first order phase transition with a jump from a zero magnetization state into the fully magnetized state at finite temperature. Dynamically, however, we find that the system becomes frozen into domains. The domain walls are made of perfectly straight segments, and domain growth appears frozen within the time scales studied with Monte Carlo simulations. This dynamical obstruction has its origin in the topology of the allowed reconfigurations in phase space, which consist of updates of closed loops of spins. As a consequence of the dynamical obstruction, there exists a dynamical temperature, lower than the (avoided) static critical temperature, at which the system is seen to jump from a ``supercooled liquid'' to a ``polycrystalline'' phase. In contrast, for antiferromagnetic interactions, we argue that the system orders for infinitesimal coupling because of the constraint, and we observe no interesting dynamical effects

Regional disparities and industrial structure: territorial capital and productivity in Italian firms

We investigate the role of Territorial Capital (TC) on the productivity of Italian firms, constructing indicators for eight dimensions of TC in a first attempt to capture a wide variety of regional resources. When imposing homogeneous TC effects on all firms, we find that technological, social, institutional, financial and infrastructure capital drive productivity. However, only technological and artistic capital contribute to reduce regional disparities. Across industries, financial capital and infrastructure increase productivity in companies operating in a wide range of sectors. Industrial policies should consider sectoral heterogeneity and North-South differences to effectively boost productivity performance

High temperature onset of field-induced transitions in the spin-ice compound Dy2Ti2O7

We have studied the field-dependent ac magnetic susceptibility of single crystals of Dy2Ti2O7 spin ice along the [111] direction in the temperature range 1.8 K - 7 K. Our data reflect the onset of local spin ice order in the appearance of different field regimes. In particular, we observe a prominent feature at approximately 1.0 T that is a precursor of the low-temperature metamagnetic transition out of field-induced kagome ice, below which the kinetic constraints imposed by the ice rules manifest themselves in a substantial frequency-dependence of the susceptibility. Despite the relatively high temperatures, our results are consistent with a monopole picture, and they demonstrate that such a picture can give physical insight to the spin ice systems even outside the low-temperature, low-density limit where monopole excitations are well-defined quasiparticles

Molecular random tilings as glasses

We have recently shown [Blunt et al., Science 322, 1077 (2008)] that p-terphenyl-3,5,3',5'-tetracarboxylic acid adsorbed on graphite self-assembles into a two-dimensional rhombus random tiling. This tiling is close to ideal, displaying long range correlations punctuated by sparse localised tiling defects. In this paper we explore the analogy between dynamic arrest in this type of random tilings and that of structural glasses. We show that the structural relaxation of these systems is via the propagation--reaction of tiling defects, giving rise to dynamic heterogeneity. We study the scaling properties of the dynamics, and discuss connections with kinetically constrained models of glasses.Comment: 5 pages, 5 figure

Quality of institutions and productivity of State-Invested Enterprises: International evidence from major telecom companies

The quality of institutions is at the core of the differences in the growth of income and productivity of nations. A growing body of evidence shows how this is also true at the firm level. After taking stock of earlier theoretical and empirical literature on the efficiency of state-owned versus private enterprises, while we consider ownership as the core internal governance mechanism of firms, we add quality of government as a determinant of the external institutional environment. To disentangle the effect of internal and external institutions on firms' productivity, we use different sets of ownership and institutional environment indicators. After having identified the top 350 private, state-invested (i.e. partially state-owned)and state-owned enterprises in the telecommunications industry in EU28 and in more than 60 other countries between 2007 and 2015, we empirically investigate models of firms' productivity augmented with ownership and quality of government. Our findings suggest that, after controlling for the regulatory and competitive conditions at the country level, on average, public ownership has a negative impact on firm-level TFP. This effect is however mitigated by high external institutional quality and even reversed in some countries with a particularly favourable institutional environment

Dynamics of single polymers under extreme confinement

We study the dynamics of a single chain polymer confined to a two dimensional cell. We introduce a kinetically constrained lattice gas model that preserves the connectivity of the chain, and we use this kinetically constrained model to study the dynamics of the polymer at varying densities through Monte Carlo simulations. Even at densities close to the fully-packed configuration, we find that the monomers comprising the chain manage to diffuse around the box with a root mean square displacement of the order of the box dimensions over time scales for which the overall geometry of the polymer is, nevertheless, largely preserved. To capture this shape persistence, we define the local tangent field and study the two-time tangent-tangent correlation function, which exhibits a glass-like behavior. In both closed and open chains, we observe reptational motion and reshaping through local fingering events which entail global monomer displacement.Comment: 22 pages, 18 figures, slightly extended version to appear in JSTA

Quantum dynamics of a domain wall in the presence of dephasing

We compare quantum dynamics in the presence of Markovian dephasing for a particle hopping on a chain and for an Ising domain wall whose motion leaves behind a string of flipped spins. Exact solutions show that on an infinite chain, the transport responses of the models are nearly identical. However, on finite-length chains, the broadening of discrete spectral lines is much more noticeable in the case of a domain wall.This work was supported in part by the ARO grant W911NF-14-1-0272, the NSF grant PHY-1416578, and EPSRC grants EP/K028960/1 and EP/M007065/1

Unconventional magnets in external magnetic fields

This short review surveys phenomena observed when a magnetic field is applied to a system of localised spins on a lattice. Its focus is on frustrated magnets in dimension $d \geq 2$. The interplay of field and entropy is illustrated in the context of their unusual magnetocaloric properties, where field-tuned degeneracies assert themselves. Magnetisation plateaux can reveal the physics of fluctuations, with unusual excitations (such as local modes, extended string defects or monopoles) involved in plateau termination. Field-tuning lattice geometry is the final topic, where mechanisms for dimensional reduction and conversion between different lattice types are discussed.Comment: Plenary Talk at HFM 2008 Conferenc

Spin Dynamics at Very Low Temperature in Spin Ice Dy2_2Ti2_2O7_7

We have performed AC susceptibility and DC magnetic relaxation measurements on the spin ice system Dy$_2$Ti$_2$O$_7$ down to 0.08 K. The relaxation time of the magnetization has been estimated below 2 K down to 0.08 K. The spin dynamics of Dy$_2$Ti$_2$O$_7$ is well described by using two relaxation times ($\tau_{\rm S}$ (short time) and $\tau_{\rm L}$ (long time)). Both $\tau_{\rm S}$ and $\tau_{\rm L}$ increase on cooling. Assuming the Arrhenius law in the temperature range 0.5-1 K, we obtained an energy barrier of 9 K. Below 0.5 K, both $\tau_{\rm S}$ and $\tau_{\rm L}$ show a clear deviation from the thermal activated dynamics toward temperature independent relaxation, suggesting a quantum dynamics.Comment: 4 page